Glossary to read first

How to use this glossary: you do not need to read it all at once. Each chapter also has its own short term cards at the top, so it is enough to refer back here only when something feels unfamiliar.

Naphtha

A relatively light mixed hydrocarbon fraction obtained from crude oil or secondary processes. Not the name of a single molecule.

Hydrocarbon

A molecule made mainly of carbon (C) and hydrogen (H).

Fraction

A range of components with similar boiling points, cut out together by distillation.

Pure compound

A substance, like water or hexane, that can be captured by one chemical formula or one kind of molecule.

Carbon number

How many carbon atoms a molecule contains. More carbons generally means heavier.

Saturated

A structure where the carbons are connected mainly by single bonds. Common in paraffins and naphthenes.

Cyclic

A structure where the molecule forms a ring. A ring does not automatically mean aromatic.

Aromatics

Molecules containing a benzene ring. Density and octane tendency tend to run higher.

PNA

Short for Paraffins / Naphthenes / Aromatics — a three-way split for reading naphtha at a glance.

Volatility

How readily a liquid turns into vapour. Lighter components are generally more volatile.

IBP

Initial Boiling Point. The temperature at which distillate first starts coming over.

FBP

Final Boiling Point. The temperature at which the last of the distillate finishes coming over.

Cut

The range, from where to where, that is carved out as a product during distillation.

Hydrotreating

Pretreatment that uses hydrogen to remove sulphur, nitrogen, and other species that would poison downstream catalysts.

Isomerization

Rearranging a molecule's skeleton while keeping its molecular formula unchanged.

Reforming

An operation that pushes heavy naphtha toward higher octane. Aromatics and hydrogen tend to appear as products.

Steam cracking

A high-temperature process that breaks molecules into smaller ones, such as ethylene and propylene.

Octane number

A measure of how resistant a gasoline is to knocking.

SDS

Safety Data Sheet — the document describing properties, hazards, and first-aid measures for handling a substance safely.

Map of this course

There are five viewpoints that we keep reusing throughout the course.

  • Think of naphtha as the name of a fraction, not the name of a single molecule.
  • As the carbon number grows, compounds generally get heavier, boiling points rise, and volatility drops.
  • Looking at PNA gives you a quick read on lightness, density, and octane tendency.
  • Move the cut lighter or heavier and the best-fit downstream process shifts with it.
  • Do not memorise hydrotreating, isomerization, reforming, and steam cracking as one lump — distinguish them by what chemical operation each one performs.
Concept diagram: naphtha is cut out of crude oil and connects through to PNA, distillation cuts, and downstream processes
Having the map first makes it much easier to keep the details straight.

Chapters

Tips for reading the course

  • Do not worry about memorising exact temperatures or measured values from the start. First, get comfortable with "which way does it move?"
  • If you run into an unfamiliar term, hover the dotted underline in the body text or check the glossary cards at the top of the chapter.
  • In the reactions chapter, first distinguish "keeps the same molecular formula but changes shape" from "breaks the molecule into smaller pieces." That alone keeps things from blurring together.
  • For real-world safety and product specifications, always defer to the SDS, analytical data, and in-house specifications over what this course says.